Crystallography of the martensitic transformation between Ni2In-type hexagonal and TiNiSi-type orthorhombic phases

نویسندگان

چکیده

MnMX (M = Co or Ni, X Si Ge) alloys, experiencing structural transformation between Ni2In-type hexagonal and TiNiSi-type orthorhombic phases, attract considerable attention due to their potential applications as room-temperature solid refrigerants. Although lots of studies have been carried out on how tune this obtain large entropy change in a wide temperature region, the crystallography martensitic is still unknown. The biggest obstacle for investigation bulk sample, which phases coexist, because alloys will fragment into powders after transformation. For reason, we carefully be slightly below 300 K. In that case, sample with small amounts distributed matrix obtained. Most importantly, there are no cracks two phases. It facilities us investigate microstructure using electron microscope. obtained results indicate orientation relationship structures [42¯2¯3]h//[120]o & (011¯0)h//(001)o habit plane {2¯113.26}h. WLR theory also adopted calculate plane. calculated result agrees well measured one. Our work reveals hexagonal-orthorhombic first time helpful understanding transformation-associated physical effects alloys.

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ژورنال

عنوان ژورنال: Journal of Materials Science & Technology

سال: 2022

ISSN: ['1941-1162', '1005-0302']

DOI: https://doi.org/10.1016/j.jmst.2021.06.051